How To Remove Samsung Account On The Galaxy S5

Go to Settings > Accounts & Sync > Samsung Account

Scroll to the bottom of the page, and tap Remove Samsung Account. A small notification will be displayed notifying you that you are about to lose your data. Tap Continue to move on in the process.

Enter your password, and follow the onscreen procedure to unlink the current Samsung account. 

To create a new account tap Add Account > Samsung Account > Accept the TOS. Follow the on-screen instructions. 

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